057 mg·kg-1 ww) were lower than those in the muscles of marbled rockcod (∑REE = 0.540 mg·kg-1 ww). The situation was analogous in the mammals, with the REE concentrations in grey seal fur (∑REE = 0.489 mg·kg-1 dw) and excrement (∑REE = 0.676 mg·kg-1 dw) being lower than those found in the fur (∑REE = 10.1 mg·kg-1 dw) and excrement (∑REE = 83.6 mg·kg-1 dw) of the elephant seal. The LREE/HREE partition coefficients in the grey seal excrement (3.37) and its fur (4.00), but also in the faeces of the elephant seal (2.63) and its fur (2.65), indicate that in each species the process of elimination from the body occurs in similar proportions.Climate change due to greenhouse gas (GHG) emissions is one of the global environmental matters of the 21st century. Biochar (BC) amendments have been proposed as a potential solution for improving soil quality and to mitigate GHGs emissions. Therefore, we evaluated the influence of different BCs on soil CO2 and N2O emissions in an outdoor pot experiment. The soil was mixed with three different types of BCs; bamboo, hardwood, and rice straw BCs as BB, BH, and BR, respectively, and control as B0 with four levels (0, 5, 20, and 80 g kg-1 of soil). Gas samples were collected on a bi-monthly basis for six months. A polyvinyl chloride (PVC) static chamber was placed on each replicate to collect the gas samples at 15, 30, 45, and 60 min, respectively. Compared to B0, the lowest cumulative N2O emissions were observed in BH80 (11%) followed by BH20, BH5, and BR80. However, for cumulative CO2 emissions, B0 and BC treatments showed no significant differences except for BB80 (>11%) and BB5 ( less then 2%). BC type and level both had a significant (P less then 0.001) impact on the cumulative N2O emissions with a significant interaction (P less then 0.001). However, cumulative CO2 emissions were unaffected by BC type but BC level showed a significant influence on cumulative CO2 emissions (P less then 0.05) and there was a significant (P less then 0.001) interaction between the BC type and level on cumulative CO2 emissions. Overall, higher doses of BR and BB showed a pronounced effect on soil pH over BH. The soil pH and moisture showed a negative correlation with N2O emissions whereas soil temperature showed a positive correlation with the cumulative fluxes of N2O. selleck chemical Our results demonstrate that BC incorporation to soil may help to mitigate GHGs emissions but its influence may vary with BC type and level under different conditions and soil type.This study accurately assessed microcystin-LR (MCLR)-trapping capabilities of diverse biochars based on sorption and sequential desorption (SDE), and elucidated MCLR sorption-desorption mechanisms from novel views of sorption domains and site energy distribution along sorption-SDE process. Results showed that maize straw biochar (MSB) and chicken manure biochar (CMB) excelled in trapping MCLR (91.0%-97.4% and 85.7%-96.4%, respectively, at 60-600 μg/L of initial MCLR amount), followed by their respective HCl-treated ones (HCMB, HSMB), while HCl-treated bamboo biochar and pine sawdust biochar poorly trapped MCLR (48.9%-77.8% for HBB, 22.6%-67.2% for HPSB). Non-partition sorption domains (NPSD) contributed more than partition sorption domain (PSD) to MCLR sorption by each biochar. Higher NPSD contribution to MCLR sorption in CMBs and MSBs than other biochars resulted from their higher pHPZC and mesoporosity, which provided stronger electrostatic and pore-filling interaction for MCLR. Desorption hysteresis was weaken with rising aqueous MCLR amount for most biochars. Along SDE process, remaining MCLR in PSD of MSBs, HPSB and HBB could transfer to NPSD, thus desorption ratio continuously decreased with increasing desorption cycle. Differently, remaining MCLR in NPSD of CMBs converted into PSD during 1st-3rd desorption, causing fluctuated desorption ratio without obvious decrease as desorption cycle increased. These implied that MCLR in PSD was more easily desorbed than NPSD for each biochar. Site energy distribution dynamics supported the results of PSD and NPSD contribution changes along SDE. This study was greatly implicated in cost-efficient emergent MCLR-pollution remediation and deeply understanding MCLR sorption-desorption mechanisms of diverse biochars.We compared long-term (1977 to 2014) trends in concentrations of PFAS in eggs of the marine sentinel species, the Northern gannet (Morus bassanus), from the Irish Sea (Ailsa Craig) and the North Sea (Bass Rock). Concentrations of eight perfluorinated carboxylic acids (PFCAs) and three perfluorinated sulfonates (PFSAs) were determined and we report the first dataset on PFAS in UK seabirds before and after the PFOS ban. There were no significant differences in ∑PFAS or ∑PFSAs between both colonies. The ∑PFSAs dominated the PFAS profile (>80%); PFOS accounted for the majority of the PFSAs (98-99%). In contrast, ∑PFCAs concentrations were slightly but significantly higher in eggs from Ailsa Craig than in those from Bass Rock. The most abundant PFCAs were perfluorotridecanoate (PFTriDA) and perfluoroundecanoate (PFUnA) which, together with PFOA, comprised around 90% of the ∑PFCAs. The ∑PFSAs and ∑PFCAs had very different temporal trends. ∑PFSAs concentrations in eggs from both colonies increased significantly in the earlier part of the study but later declined significantly, demonstrating the effectiveness of the phasing out of PFOS production in the 2000s. In contrast, ∑PFCAs concentrations in eggs were constant and low in the 1970s and 1980s, suggesting minimal environmental contamination, but residues subsequently increased significantly in both colonies until the end of the study. This increase appeared driven by rises in long chain compounds, namely the odd chain numbered PFTriDA and PFUnA. PFOA, had a very different temporal trend from the other dominant acids, with an earlier rise in concentrations followed by a decline in the last 15 years in Ailsa Craig; later temporal trends in Bass Rock eggs were unclear. Although eggs from both colonies contained relatively low concentrations of PFAS, the majority had PFOS residues that exceeded a suggested Predicted No Effect Concentration and ~ 10% of the eggs exceeded a suggested Lowest-Observable-Adverse-Effect.