36 eV. In addition, the electronic properties, namely the Bader charge, charge density difference, partial density of states, and crystal orbital Hamilton population, of the TM@GY catalysts were analyzed in detail, and the results further confirmed that Mn@GY was an efficient electrocatalyst. The insights obtained from this comprehensive study can provide useful guidelines for designing new and efficient electrocatalysts.Superhydrophobic materials have been widely reported throughout the scientific literature. Their properties originate from a highly rough morphology and inherently water repellent surface chemistry. Despite promising an array of functionalities, these materials have seen limited commercial development. This could be attributed to many factors, like material compatibility, low physical resilience, scaling-up complications, etc. In applications where persistent water contact is required, another limitation arises as a major concern, which is the stability of the air layer trapped at the surface when submerged or impacted by water. This review is aimed at examining the diverse array of research focused on monitoring/improving air layer stability, and highlighting the most successful approaches. The reported complexity of monitoring and enhancing air layer stability, in conjunction with the variety of approaches adopted, results in an assortment of suggested routes to achieving success. The review is addressing the challenge of finding a balance between maximising water repulsion and incorporating structures that protect air pockets from removal, along with challenges related to the variant approaches to testing air-layer stability across the research field, and the gap between the achieved progress and the required performance in real-life applications.Direct and sensitive short-wavelength ultraviolet (UVC) dosimeters could provide a safer disinfection environment against viruses. We developed direct, quantitative, specific and highly sensitive UVC dosimeters based on DNA nanostructure-modified graphene field-effect transistors. Detectable doses of the dosimeters range from 0.005 to 6 kJ m-2 and such dosimeters have at least 5 times better sensitivity than the current direct UV dosimeters.The rush to synthesize novel two-dimensional (2D) materials has excited the research community studying ternary-layered carbide and nitride compounds, known as MAX phases, for the past two decades in the quest to develop new 2D material precursors. The objective of this study is to expand the family of MAX phases and to investigate their feasible exfoliation to generate 2D systems. Ivosidenib To expand the family of MAX phases, we conduct systematic and fundamental research using elemental information and data from high-throughput density functional theory calculations performed on 1122 MAX candidates. Our results suggest that 466 MAX compounds can be synthesized, among which 136 MAX phases can be exfoliated to produce 26 MXenes. We investigate the transition metal or A elements that could be suitable for the formation of novel MAX phase carbides or nitrides and determine promising MAX phases that can be exfoliated to form 2D systems.Group-10 transition metal dichalcogenides (TMDs) are rising in prominence within the highly innovative field of 2D materials. While PtS2 has been investigated for potential electronic applications, due to its high charge-carrier mobility and strongly layer-dependent bandgap, it has proven to be one of the more difficult TMDs to synthesise. In contrast to most TMDs, Pt has a significantly more stable monosulfide, the non-layered PtS. The existence of two stable platinum sulfides, sometimes within the same sample, has resulted in much confusion between the materials in the literature. Neither of these Pt sulfides have been thoroughly characterised as-of-yet. Here we utilise time-efficient, scalable methods to synthesise high-quality thin films of both Pt sulfides on a variety of substrates. The competing nature of the sulfides and limited thermal stability of these materials is demonstrated. We report peak-fitted X-ray photoelectron spectra, and Raman spectra using a variety of laser wavelengths, for both materials. This systematic characterisation provides a guide to differentiate between the sulfides using relatively simple methods which is essential to enable future work on these interesting materials.Glioma stem cells (GSCs) and their complex microenvironment play a crucial role in the high invasion of cancer and therapeutic resistance and are considered to be the most likely cause of cancer relapse. We constructed a biomimetic vehicle (LDL-SAL-Ang) based on a low density lipoprotein triggered by Angiopep-2 peptide and ApoB protein, to improve the transport of an anti-GSC therapeutic agent into the brain. The LDL-SAL-Ang showed significant inhabitation for GSC microsphere formation and induced the highest apoptotic rate in two types of GSCs. LDL-SAL-Ang reduced the number of GSC-derived endothelial tubules at a lower drug concentration and inhibited endothelial cell migration and angiogenesis. The pharmacokinetic analysis showed that the brain tissue uptake rate (% ID g-1) for LDL-SAL-Ang was significantly enhanced at 0.45. For anti-glioblastoma activity in vivo, the median survival time of LDL-SAL-Ang plus temozolomide group was 47 days, which were significantly increased compared with the control or temozolomide only groups. The endogenous biomimetic nanomedicine that we designed provides a potential approach to improve treatments for intracranial tumors and reduced neurotoxicity of nanomedicine.X-ray crystallography is an invaluable tool in design and development of organometallic catalysis, but application typically requires species to display sufficiently high solution concentrations and lifetimes for single crystalline samples to be obtained. In crystallo organometallic chemistry relies on chemical reactions that proceed within the single-crystal environment to access crystalline samples of reactive organometallic fragments that are unavailable by alternate means. This highlight describes approaches to in crystallo organometallic chemistry including (a) solid-gas reactions between transition metal complexes in molecular crystals and diffusing small molecules, (b) reactions of organometallic complexes within the extended lattices of metal-organic frameworks (MOFs), and (c) intracrystalline photochemical transformations to generate reactive organometallic fragments. Application of these methods has enabled characterization of catalytically important transient species, including σ-alkane adducts of transition metals, metal alkyl intermediates implicated in metal-catalyzed carbonylations, and reactive M-L multiply bonded species involved in C-H functionalization chemistry.