Significant correlation between salinity and optical parameters (SUVA254, S275-295, S350-400, Cprotein/Chumic) indicated that water mixing strongly influenced the distributions of these optical parameters. The bioreactivity and photoreactivity of DOM varied depending on the source material, and the autochthonous protein-like DOM was more prone to biodegradation than the terrestrial DOM. The photodegradation processes acted preferentially on the CDOM than the colorless DOM. These results demonstrated that the optical parameters exhibited distinct changes during the mixing and the biodegradation and photodegradation processes and explained the seasonal distribution of DOM in the ECS and the YS.

Investigations on the potential effects of high air pollution exposure before pregnancy on adverse pregnancy outcomes are limited, and it is unknown whether air quality standards looser than that set by World Health Organization (WHO) still can provide sufficient protection pregnant women from adverse pregnancy outcomes.

To evaluate the potential effects of high ambient air pollution around pregnancy on preterm birth (PTB) and low birth weight (LBW), and assess the risk of PTB and LBW associated with air pollutants with reference to different air quality standards of WHO and China.

Our study leveraged 10,960 pregnant women from the Project ELEFANT. Daily average particulate matter with an aerodynamic diameter of ≤2.5μm (PM

) and ≤10μm (PM

), nitrogen dioxide (NO

), sulfur dioxide (SO

), carbon monoxide (CO) and ozone (O

) concentrations were collected based on Chinese Air Quality Reanalysis datasets. Hazard ratios (HR) of PTB and LBW were estimated for maternal PM

, PM

, NO

, SO

, CO and O

exf adverse pregnancy outcomes associated with ambient air pollution in areas with high air pollution levels.Raptors (birds of prey and owls) have been widely used as suitable bioindicators of environmental pollution. They occupy the highest trophic positions in their food chains and are documented to bioaccumulate high concentrations of persistent pollutants such as toxic metals and legacy persistent organic pollutants (POPs).Whereas raptors played a critical role in developing awareness of and policy for chemical pollution, they have thus far played a much smaller role in current research on contaminants of emerging concern (CECs). Given the critical knowledge obtained from monitoring ‘legacy contaminants’ in raptors, more information on the levels and effects of CECs on raptors is urgently needed. This study critically reviews studies on raptors from Europe reporting the occurrence of CECs with focus on the investigated species, the sampled matrices, and the bioanalytical methods applied. Based on this, we aimed to identify future needs for monitoring CECs in Europe. Perfluoroalkyl substances (PFASs), novel flame retardants (NFRs), and to a lesser extent UV-filters, neonicotinoids, chlorinated paraffins, parabens and bisphenols have been reported in European raptors. White-tailed Eagle (Haliaeetus albicilla), Peregrine falcon (Falco peregrinus) and Northern goshawk (Accipiter gentilis) were the most frequently studied raptor species. Among matrices, eggs, feathers and plasma were the most widely employed, although the potential role of the preen gland as an excretory organ for CECs has recently been proposed. This review highlights the following research priorities for pollution research on raptors in Europe 1) studies covering all the main classes of CECs; 2) research in other European regions (mainly East Europe); 3) identification of the most suitable matrices and species for the analysis of different CECs; and 4) the application of alternative sample treatment strategies (e.g. QuEChERS or pressurized liquid extraction) is still limited and conventional solvent-extraction is the preferred choice.Water scarcity problems are a national agenda that must be prioritized. Thailand is an agricultural country with agriculture consuming a large amount of water. Sustainable water management for the agricultural sector is urgently needed. This study assessed the impacts of water consumption by agricultural products using a water scarcity footprint (WSF) assessment. This study presents the use of the growing season available water remaining characterization factors (AWARE CFs) of specific crops, based on growth months of that crop, instead of the annual AWARE CFs of agricultural products to assess the value of this approach for an appropriate assessment of water resource and the planning of crop production priorities. The original marginal AWARE CF was considered for determining the growing season AWARE CFs of major rice, second rice, sugarcane, maize, and cassava in 25 Thai watersheds. The growing season AWARE CFs of the food crops were used to determine their WSFs for the 25 Thai watersheds. The growing season AWARE CFs of major rice, second rice, sugarcane, maize, and cassava for Thailand were 1.74, 11.5, 6.01, 3.28, and 7.96 m3 world-eq. per m3 consumed, respectively. There were statistical differences between the means of annual AWARE CFs and growing season AWARE CFs for all Thai food crops in almost all watersheds. The WSFs using growing season AWARE CFs of major rice, second rice, sugarcane, maize, and cassava were 0.05-3.66, 1.10-193, 0.51-7.99, 1.09-8.28, and 1.65-30.3 m3 world-eq. per kilogram, respectively. This work identified suitable watersheds for growing food crops and compiled them as databases for the use of zoning food crop cultivation by the Thai government. Regarding WSF values, the least suitable watershed for growing major rice, second rice, sugarcane, and cassava was the Petchaburi watershed. The least suitable watershed for growing maize was the Chao Phraya watershed.Using catalytic converters is one of the most effective methods to control vehicle emissions. A washcoat of cerium oxide-zirconia (CeO2-ZrO2) has been used to enhance the performance of the catalytic converter device. To date, the prevalence of this material in the environment has not been assessed. Selleck TGF-beta inhibitor In this study, we present evidence of the existence of inhalable zirconia in urban dust. Samples of the washcoat, exhaust pipe, topsoil, and road dust were analyzed by X-ray fluorescence, X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, photoluminescence (PL) spectroscopy, and thermally stimulated luminescence (TSL). The results showed a CeO2-ZrO2 phase separation after sintering. This causes the emission of ZrO2, CeO2, and CeZrOx particles smaller than 1 μm, which can likely reach the alveolar macrophages in the lungs. The Ce-Zr content in road dust exceeds geogenic levels, and a significant correlation of 0.87 (p less then 0.05) reflects a common anthropic source. Chronic exposure to such refractory particles may result in the development of non-occupational respiratory diseases.