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  • Franklin Frandsen posted an update 6 days, 11 hours ago

    The simultaneous sorption behaviors of four analytes from the UV filters group, benzophenone (BPh), 4-methylbenzylidene camphor (4MBC), benzophenone 3 (BPh3), and benzophenone 2 (BPh2) on virgin and aged high-density polyethylene (HDPE) with a particle size of 125 μm in milliQ and river water were examined in this study. The aging processes of HDPE particles were carried out with the use of simulated sunlight. Conducted research revealed that the sorption of UV filters on HDPE particles follows pseudo-second-order kinetics. A Temkin isothermal model best described the adsorption process for 4BMC, BPh, BPh3, BPh2 on aged HDPE in river water, and 4MBC, BPh, BPh3 on virgin HDPE in milliQ water. The adsorption of BPh2 onto virgin MPs in milliQ water was consistent with the Langmuir isothermal model. Environmental conditions and physicochemical properties of analytes influenced the sorption mechanism between UV filters and MPs particles. It was observed that the main mechanisms responsible for the sorption of BPh, 4MBC, BPh3, and BPh2 on the surface of HDPE are hydrophobic interactions, that may change through the involvement of electrostatic interactions.Solar grade silicon (SoGSi) is a key material for the development of crystalline silicon photovoltaics (PV), which is expected to reach the tera-watt level in the next years and around 50TW in 2050. Upgraded metallurgical grade silicon (UMGSi) has already demonstrated to be a viable alternative to standard polysilicon in terms of cost and quality. This study presents the life cycle assessment (LCA) of UMG obtained by the FerroSolar process. Moreover, it shows the environmental impacts of PV modules and electricity generation based on this material. For this, an exhaustive review of the life cycle inventory (LCI) of PV value chain, from metallurgical grade silicon (MG-Si) down to electricity generation, has been carried out updating inputs for all processes. The Balance of System (BoS) has also been updated with current state of the art data for a fixed open ground large PV site (100 MWpk). Two different electricity mixes, with low and high carbon intensities, have been considered. The results reveal that for PV electricity generation using UMG-Si instead of polysilicon leads to an overall reduction of Climate change (CC) emissions of over 20%, along with an improvement of the Energy Payback Time (EPBT) of 25%, achieving significantly low values, 12 gCO2eq/kWhe and 0.52 years, respectively. Moreover, it is shown that UMG silicon feedstock is not the main contributor to the carbon and energy footprint of the produced electricity, leaving the first place to PV module manufacturing.RNA-based high-throughput sequencing is a valuable tool in the discernment of the implication of metabolically active bacteria during composting. In this study, “alperujo” composting was used as microbial model for the elucidation of structure-function relationships with physicochemical transformation of the organic matter. DNA and RNA, subsequently retrotranscribed into cDNA, were isolated at the mesophilic, thermophilic and maturation phases. 16S rRNA gene was amplified by quantitative PCR (qPCR) and Illumina MiSeq platform to assess bacterial abundance and diversity, respectively. The results showed that the abundance of active bacteria assessed by qPCR was maximum at thermophilic phase, which confirm it as the most active stage of the process. Y-27632 in vivo Concerning diversity, Proteobacteria, Firmicutes, Bacteroidetes and Actinobacteria were the main phyla presented in composts. Concomitantly, three different behaviours were observed for bacterial dynamics some genera decreased during the whole process meanwhile others proliferated only at thermophilic or maturation phase. Statistical correlation between physicochemical transformations of the organic matter and bacterial diversity revealed bacterial specialisation. This result indicated that specific groups of bacteria were only involved in the organic matter degradation during bio-oxidative phase or humification at maturation. Metabolic functions predictions confirmed that active bacteria were mainly involved in carbon (C) and nitrogen (N) cycles transformations, and pathogen reduction.The maritime industry plays a key role in reducing greenhouse gas (GHG) emissions, as an effort to combat the global issue of climate change. The International Maritime Organization (IMO) is targeting a 50% reduction in GHG emissions by 2050 compared to 2008. To measure Singapore’s progress towards this target, we have conducted a comprehensive analysis of carbon dioxide (CO2) emissions from the Western Singapore Straits based on the voyage data from Automatic Identification System (AIS) and static information from Singapore Maritime Data Hub (SG-MDH). Two methodologies, the MEET and TRENDS frameworks were applied to estimate the emission volume per vessel per hour. The data analysis results were next aggregated and visualised to answer key questions such as How did the carbon emission level change from 2019 to 2020, in general, and for specific vessel types? What are the top vessel types and flags that had the highest carbon emissions? Did the traffic volume and emission level decrease during the Circuit Breaker period in 2020? The results of this study can be used to review Singapore’s emission control measures and will be of value to the Maritime and Port Authority (MPA) of Singapore responsible for managing CO2 emissions at the Singapore Port.In snow and ice, light-absorbing particles (LAPs), such as black carbon (BC) and dust, accelerate the melting of Third Pole glaciers (TPGs). In this study, we revaluated LAP concentrations in the snow pits of TPGs (SP-TPGs), measured LAP mass absorption cross-sections (MACs), and simulated their effects on glacier darkening and melting based on the Spectral Albedo Model for Dirty Snow and a surface energy and mass balance model. The results indicated that because of their short distances to emission sources, the average BC concentrations measured in snow pits in the periphery of Third Pole were much higher than those measured in the inland Tibetan Plateau, and the average dust concentrations generally decreased from north to south. The average MACs of BC in the SP-TPGs varied from 3.1 to 7.7 m2 g-1 at 550 nm, most of the average spectral values were comparable in the visible and near-infrared bands to those calculated by Mie theory, except those in Urumqi Glacier No. 1 (UR), Syek Zapadniy Glacier (SZ), and Laohugou Glacier No.

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